Lao-for-Beginners is and excellent course to get you started. It covers all four aspects of the language: speaking, listening, reading and writing (if bought in conjuction with the complementary audio lessons). The book is easy to use and includes an introduction the writing system, conversations to listening and comprehension, and essential grammar points.
Lonely-Planet-Lao-Phrasebook is the most easy to use and practical phrasebook available for the language. The pronunciation guide is excellent, and the handy culture notes dispersed throughout the book, make the ideal travel companion if you're in the country or in North East Thailand.
Internet freebies:
The following website provides free educational information regarding the teachings of the Bible, with a page in the language and the same information on a page in English. A comparison of the texts can help contribute to your language acquisition.
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